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Materials science, physics, chemistry, energies, photovoltaic

CrySaLID

Deeper understanding of Silicon (Si) crystallization in correlation and its correlation with photovoltaic properties

Although crystalline Si remains predominant at more than 90 % in PV solar cells, significant progress in terms of performance improvement and cost reduction is essential. In particular, the fundamental mechanisms of the Si crystallization are only imperfectly understood, which limits process improvement and delays the development of innovative processes.

Within this context, the CrysSaLID consortium has successfully carried out original or even unique fundamental research work, in connection with industrial questioning in order to deepen knowledge of Si crystallization and to develop predictive simulation tools. The formation of the crystal structure has been studied experimentally at different scales, in particular with a unique experiment with in situ X-ray imaging during solidification at high temperature. At the same time, 3D simulation models of crystal formation have been developed and validated experimentally.

The project

ANR programme: Generic Call for Proposals

Edition, project duration: 2014, 42 months

ANR grant: € 739,406

Coordinator:

Project region: PACA

Main publication or contribution:

  • N. Mangelinck-Noël, Étienne Pihan, Le renouveau du silicium dope les panneaux solaires, Article La Recherche N° 539, Septembre 2018.
  • Hadjer Ouaddah, Maike Becker, Thècle Riberi-Béridot, Maria Tsoutsouva, Vasiliki Stamelou, Gabrielle Regula, Guillaume Reinhart, Isabelle Périchaud, Fabrice Guittonneau, Laurent Barrallier, Jean-Paul Valade, Alexander Rack, Elodie Boller, José Baruchel and Nathalie Mangelinck-Noël, X-ray Based in Situ Investigation of Silicon Growth Mechanism Dynamics—Application to Grain and Defect Formation, Crystals 2020, 10, 555; doi:10.3390/cryst10070555

  • A. Pineau, G. Guillemot, G. Reinhart, G. Regula, N. Mangelinck-Noël, Ch.-A. Gandin, Three-dimensional cellular automaton modeling of silicon crystallization with grains in twin relationships, Acta Materialia 191 (2020) 1-15; doi: 10.1016/j.actamat.2020.03.051

Partners:

  •  EMIX entreprise, France.
  •  ARMINES-CEMEF (Centre de Mise en Forme des Matériaux), France.
  •  SIMAP (Science et Ingénierie des Matériaux et Procédés) CNRS UMR 5266, France.
  •  SINTEF independent research organisation, Norway.
  •  NTNU (Norwegian University of Science and Technology), Norway.
  •  KAU (Karlstad University), Sweden.
CrySaLID
Results of the CrySaLID project: ingot, simulations, properties and X imaging. © (a) SIMAP (b) CEMEF (c) NTNU & SINTEF (d) EMIX (e) IM2NP (f) KAU (g) IM2NP
perspectives
perspectives

The originality of the results allowed the initiation of new international and industrial projects, conferences and publications beyond the end of the project. Moreover, CrySaLID contributed to the training of young researchers and to the organisation of several popularization actions.

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